By the end of this chapter you'll be able to…

  • 1State the law of definite proportion (water H:O = 1:8)
  • 2Identify cathode rays as electrons
  • 3Name the subatomic particles and find atomic/mass number
  • 4Define valency through hydrogen
  • 5Identify cations and anions and write formulae
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Why this chapter matters
Atomic Structure explains the law of definite proportion, the discovery of the electron (cathode rays) and how valency builds chemical formulae — the foundation of chemistry and directly tested book-back content in the TN Class 8 exam.

Before you start — revise these

A 5-minute refresher here will save you 30 minutes of confusion below.

Atomic Structure — Class 8 Science (Samacheer Kalvi)

TN State Board (Samacheer Kalvi) Class 8 Science, Chemistry — Chapter 12. Inside the atom — particles, laws and valency.


1. About this chapter

This chapter covers the law of definite proportion, cathode rays, the subatomic particles, atomic number and mass number, valency, ions, and writing chemical formulae.

2. Laws of chemical combination

  • Law of definite proportion: a compound always contains the same elements combined in the same proportion by mass, whatever its source. For example, carbon dioxide from any source has the same ratio of carbon and oxygen; in water, hydrogen and oxygen combine in the ratio 1 : 8 by mass.

3. Subatomic particles

ParticleChargeLocationNote
Proton+1nucleus
Neutron0nucleus
Electron−1shellscathode rays are streams of electrons
  • Atomic number (Z) = number of protons. Mass number (A) = protons + neutrons.
  • Electrons fill shells (K, L, M…) holding 2, 8, 8… electrons.

4. Valency, ions and formulae

  • Valency is the number of hydrogen atoms that combine with (or replace) one atom of an element (e.g., oxygen valency 2 in H₂O).
  • Ions: a cation (+) forms by losing electrons; an anion (−) forms by gaining electrons.
  • Chemical formula: cross-multiply the valencies, e.g. Na (1) and O (2) → Na₂O.

5. Worked examples

Example 1. What is the ratio of hydrogen to oxygen by mass in water? 1 : 8.

Example 2. Cathode rays are made up of which particles? Negatively charged electrons.

Example 3. Write the formula of magnesium chloride (Mg valency 2, Cl valency 1). Cross-multiply → MgCl₂.

6. Book-back questions (Samacheer Kalvi)

I. Choose the correct answer

  1. The same proportion of carbon and oxygen in carbon dioxide from any source proves the law of — (a) conservation of mass / (b) definite proportion. Ans: (b) definite proportion.
  2. Cathode rays are made up of — (a) negatively charged particles / (b) positive particles. Ans: (a) negatively charged particles.
  3. In water, hydrogen and oxygen are combined in the ratio — (a) 1 : 16 / (b) 1 : 8 by mass. Ans: (b) 1 : 8.
  4. The atomic number of an atom represents the number of — (a) neutrons / (b) protons. Ans: (b) protons.

II. Fill in the blanks 5. A positively charged ion is called a cation and a negatively charged ion is an anion. 6. An electron is a negatively charged particle. 7. The valency of an element is the number of hydrogen atoms that combine with one atom of it.

7. Common mistakes

  • Mistake: Counting electrons for the atomic number. Fix: Atomic number = number of protons.
  • Mistake: Saying cathode rays are positive. Fix: Cathode rays are negatively charged (electrons).
  • Mistake: Forgetting the 1 : 8 ratio in water. Fix: In water, H : O = 1 : 8 by mass (law of definite proportion).

8. Quick revision

  • Chemistry Ch 12 · laws, particles, valency, formulae.
  • Law of definite proportion: fixed ratio by mass (water H : O = 1 : 8).
  • Cathode rays = electrons (negative); proton (+) and neutron (0) in nucleus.
  • Z = protons; A = protons + neutrons; shells 2, 8, 8.
  • Valency = combining hydrogen atoms; cation (+) loses e⁻, anion (−) gains; formula by cross-multiplying valencies.

Key formulas & results

Everything you need to memorise, in one card. Screenshot this for revision.

Law of definite proportion
fixed ratio by mass (water H:O = 1:8)
Same in any sample.
Atomic / mass number
Z = protons; A = protons + neutrons
Cathode rays = electrons.
Valency
number of hydrogen atoms that combine with one atom
Decides the formula.
Ions
cation + (loses e⁻); anion − (gains e⁻)
Charged atoms.
⚠️

Common mistakes & fixes

These are the exact errors that cost students marks in board exams. Read them once, save yourself the trouble.

WATCH OUT
Counting electrons for the atomic number
Atomic number = number of protons.
WATCH OUT
Saying cathode rays are positive
Cathode rays are negatively charged (electrons).
WATCH OUT
Forgetting the 1 : 8 ratio in water
In water, H : O = 1 : 8 by mass.

Practice problems

Try each one yourself before tapping "Show solution". Active recall > rereading.

Q1EASY· MCQ
The fixed proportion of carbon and oxygen in carbon dioxide proves the law of ____.
Show solution
definite proportion.
Q2EASY· MCQ
Cathode rays are made up of ____ particles.
Show solution
negatively charged (electrons).
Q3EASY· MCQ
In water, hydrogen and oxygen combine in the ratio ____ by mass.
Show solution
1 : 8.
Q4EASY· Fill in the blanks
The valency of an element is the number of ____ atoms that combine with one atom of it.
Show solution
hydrogen.
Q5MEDIUM· Formula
Write the formula of magnesium chloride (Mg valency 2, Cl valency 1).
Show solution
Cross-multiply → MgCl₂.
Q6EASY· Concept
What is a cation?
Show solution
A positively charged ion formed by losing electrons.

5-minute revision

The whole chapter, distilled. Read this the night before the exam.

  • Chemistry Chapter 12 of Samacheer Kalvi Class 8 Science.
  • Law of definite proportion: fixed ratio by mass (water H:O = 1:8).
  • Cathode rays = electrons (negative); proton (+) and neutron (0) in nucleus.
  • Z = protons; A = protons + neutrons; shells 2, 8, 8.
  • Valency = combining hydrogen atoms.
  • Cation (+) loses electrons, anion (−) gains; formula by cross-multiplying valencies.

Tamil Nadu (TNBSE) marks blueprint

Where the marks come from in this chapter — so you can plan your prep.

Typical chapter weightage: 5-8 marks across book-back MCQ, fill-ups and formula questions

Question typeMarks eachTypical countWhat it tests
MCQ / Fill13-5Definite proportion, cathode rays, valency
Formula21Writing formulae from valency
Short Answer21Atomic/mass number, ions
Prep strategy
  • Learn the law of definite proportion (water 1:8)
  • Remember cathode rays = electrons
  • Use protons for the atomic number
  • Define valency through hydrogen and write formulae

Where this shows up in the real world

This chapter isn't just an exam topic — it lives in the world around you.

Chemistry foundation

Atomic structure underlies bonding, reactions and formulae.

Materials

Valency explains how elements combine into compounds.

Technology

Electrons and ions are central to batteries and electronics.

Exam strategy

Battle-tested tips from teachers and toppers for this chapter.

  1. Quote the water ratio (1 : 8) for definite proportion
  2. State cathode rays are negative
  3. Use protons for the atomic number
  4. Cross-multiply valencies for formulae

Going beyond the textbook

For olympiad aspirants and curious learners — topics that build on this chapter.

  • Verify the law of definite proportion using given masses.
  • Write formulae for five compounds using valencies.

Where else this chapter is tested

CBSE board isn't the only one — other exams test this chapter too.

TN Class 8 Annual ExamHigh
Foundation / NMMS ScienceMedium
School unit testsHigh

Questions students ask

The real ones — pulled from the Q&A community and tutor sessions.

That a given compound always contains its elements combined in the same fixed proportion by mass, no matter where it comes from — for example, water is always H : O = 1 : 8 by mass.

Write the symbols and their valencies, then cross-multiply the valencies to get the subscripts — for example Na (1) and O (2) give Na₂O.
Verified by the tuition.in editorial team
Last reviewed on 3 June 2026. Written and reviewed by subject-matter experts — read about our process.
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