About
Semiconductors are the backbone of modern electronics — from computer chips to smartphones. This chapter introduces the physics of semiconductors, how doping creates n-type and p-type materials, the formation and behaviour of the p-n junction, and the working of diodes and transistors.
Key Concepts
28.1 Energy Bands
| Material | Band Gap | Conductivity |
|---|---|---|
| Conductor | Overlapping bands | Very high |
| Semiconductor | ~1 eV (Si: 1.1 eV) | Moderate, increases with T |
| Insulator | > 3 eV | Very low |
28.2 Intrinsic Semiconductor
Pure semiconductor. At 300 K, for silicon: m⁻³.
- Electron concentration () = hole concentration () =
- Charge neutrality is maintained
28.3 Extrinsic Semiconductor
Doping: Adding controlled impurity to increase conductivity.
| Type | Dopant | Valency | Majority Carriers |
|---|---|---|---|
| n-type | Pentavalent (P, As, Sb) | 5 | Electrons |
| p-type | Trivalent (B, Al, Ga) | 3 | Holes |
- n-type: Electrons = majority carriers, holes = minority
- p-type: Holes = majority carriers, electrons = minority
- Extrinsic has lower resistivity than intrinsic
28.4 p-n Junction
Formation:
- Majority carriers diffuse across the junction
- Depletion region forms — contains uncompensated acceptor/donor ions
- Barrier potential develops: Si ≈ 0.7 V, Ge ≈ 0.3 V
Biasing:
| Bias | Connection | Behaviour |
|---|---|---|
| Forward | p → +, n → − | Low resistance, current flows |
| Reverse | p → −, n → + | High resistance, negligible current (leakage only) |
Diode: Allows current in one direction only — rectification.
28.5 Transistor
A three-terminal device with two p-n junctions (npn or pnp).
Configurations: Common base (CB), Common emitter (CE), Common collector (CC).
Uses: Amplification, switching, oscillation.
INTEXT QUESTIONS 28.1
Q1. At 300 K, pure silicon has m⁻³. What is the concentration of holes and electrons?
Ans: In intrinsic silicon: m⁻³.
Q2. n-type semiconductor is obtained by doping with:
Ans: (ii) Pentavalent impurity. (P, As, Sb — Group V, 5 valence electrons → extra electron).
Q3. An intrinsic semiconductor can be converted into extrinsic by addition of ______. This process is called ______.
Ans: Impurity and doping.
Q4. Electrons in n-type and holes in p-type are the ______ carriers.
Ans: Majority.
Q5. An extrinsic semiconductor has ______ resistivity compared to intrinsic.
Ans: Lower.
INTEXT QUESTIONS 28.2
Q1. Fill in the blanks:
(a) When a p-n junction forms, the majority carriers diffuse across. (b) Uncompensated ions form the depletion region. (c) Barrier potential: Si = 0.7 V, Ge = 0.3 V. (d) Electrons diffuse from n to p due to concentration difference.
Terminal Exercise
-
Distinguish between conductors, semiconductors, and insulators on the basis of energy band theory.
-
What is doping? Distinguish between n-type and p-type semiconductors.
-
Explain the formation of a p-n junction. What is a depletion region and barrier potential?
-
Draw and explain the V-I characteristics of a p-n junction diode.
-
Explain how a p-n junction diode works as a half-wave rectifier.
-
Describe the working of an npn transistor. Define and .
-
A transistor has . If the base current changes by 20 μA, find the change in collector current.
-
Why is silicon preferred over germanium for making semiconductor devices?
-
In a transistor in CE configuration, μA, mA. Find and .
-
Distinguish between Zener breakdown and avalanche breakdown.
Quick Revision
| Concept | Key Point |
|---|---|
| Intrinsic (Si, 300K) | m⁻³ |
| n-type dopant | Pentavalent (P, As, Sb) |
| p-type dopant | Trivalent (B, Al, Ga) |
| Barrier potential Si | ~0.7 V |
| Barrier potential Ge | ~0.3 V |
| Diode | Forward = ON, Reverse = OFF |
| Transistor |
