About

Semiconductors are the backbone of modern electronics — from computer chips to smartphones. This chapter introduces the physics of semiconductors, how doping creates n-type and p-type materials, the formation and behaviour of the p-n junction, and the working of diodes and transistors.


Key Concepts

28.1 Energy Bands

MaterialBand GapConductivity
ConductorOverlapping bandsVery high
Semiconductor~1 eV (Si: 1.1 eV)Moderate, increases with T
Insulator> 3 eVVery low

28.2 Intrinsic Semiconductor

Pure semiconductor. At 300 K, for silicon: m⁻³.

  • Electron concentration () = hole concentration () =
  • Charge neutrality is maintained

28.3 Extrinsic Semiconductor

Doping: Adding controlled impurity to increase conductivity.

TypeDopantValencyMajority Carriers
n-typePentavalent (P, As, Sb)5Electrons
p-typeTrivalent (B, Al, Ga)3Holes
  • n-type: Electrons = majority carriers, holes = minority
  • p-type: Holes = majority carriers, electrons = minority
  • Extrinsic has lower resistivity than intrinsic

28.4 p-n Junction

Formation:

  1. Majority carriers diffuse across the junction
  2. Depletion region forms — contains uncompensated acceptor/donor ions
  3. Barrier potential develops: Si ≈ 0.7 V, Ge ≈ 0.3 V

Biasing:

BiasConnectionBehaviour
Forwardp → +, n → −Low resistance, current flows
Reversep → −, n → +High resistance, negligible current (leakage only)

Diode: Allows current in one direction only — rectification.

28.5 Transistor

A three-terminal device with two p-n junctions (npn or pnp).

Configurations: Common base (CB), Common emitter (CE), Common collector (CC).

Uses: Amplification, switching, oscillation.


INTEXT QUESTIONS 28.1

Q1. At 300 K, pure silicon has m⁻³. What is the concentration of holes and electrons?

Ans: In intrinsic silicon: m⁻³.

Q2. n-type semiconductor is obtained by doping with:

Ans: (ii) Pentavalent impurity. (P, As, Sb — Group V, 5 valence electrons → extra electron).

Q3. An intrinsic semiconductor can be converted into extrinsic by addition of ______. This process is called ______.

Ans: Impurity and doping.

Q4. Electrons in n-type and holes in p-type are the ______ carriers.

Ans: Majority.

Q5. An extrinsic semiconductor has ______ resistivity compared to intrinsic.

Ans: Lower.


INTEXT QUESTIONS 28.2

Q1. Fill in the blanks:

(a) When a p-n junction forms, the majority carriers diffuse across. (b) Uncompensated ions form the depletion region. (c) Barrier potential: Si = 0.7 V, Ge = 0.3 V. (d) Electrons diffuse from n to p due to concentration difference.


Terminal Exercise

  1. Distinguish between conductors, semiconductors, and insulators on the basis of energy band theory.

  2. What is doping? Distinguish between n-type and p-type semiconductors.

  3. Explain the formation of a p-n junction. What is a depletion region and barrier potential?

  4. Draw and explain the V-I characteristics of a p-n junction diode.

  5. Explain how a p-n junction diode works as a half-wave rectifier.

  6. Describe the working of an npn transistor. Define and .

  7. A transistor has . If the base current changes by 20 μA, find the change in collector current.

  8. Why is silicon preferred over germanium for making semiconductor devices?

  9. In a transistor in CE configuration, μA, mA. Find and .

  10. Distinguish between Zener breakdown and avalanche breakdown.


Quick Revision

ConceptKey Point
Intrinsic (Si, 300K) m⁻³
n-type dopantPentavalent (P, As, Sb)
p-type dopantTrivalent (B, Al, Ga)
Barrier potential Si~0.7 V
Barrier potential Ge~0.3 V
DiodeForward = ON, Reverse = OFF
Transistor
Verified by the tuition.in editorial team
Written and reviewed by subject-matter experts — read about our process.
Editorial process →
Header Logo