Chemical Bonding — Class 9 Physical Science
"Atoms bond to become STABLE. The noble gases already are. Every other atom is trying to become one. This is the OCTET RULE — the central organizing principle of chemistry."
1. Why Do Atoms Bond?
Atoms bond to achieve a STABLE ELECTRONIC CONFIGURATION — usually 8 electrons in the outermost shell (OCTET). Exceptions: Hydrogen and Helium stable with 2 electrons (DUET). 'The noble gases (Group 18: He, Ne, Ar) have complete outer shells. They are UNREACTIVE. Every other atom, in some sense, is TRYING to be a noble gas.'
Three Ways to Achieve Stability
- LOSE electrons (metals — become cations). 2. GAIN electrons (non-metals — become anions). 3. SHARE electrons (non-metals with non-metals).
Kossel-Lewis Approach
G.N. Lewis and W. Kossel independently proposed: atoms achieve stability by acquiring 8 electrons in the valence shell. Lewis introduced the OCTET RULE and DOT STRUCTURES.
2. Ionic (Electrovalent) Bond — Electron TRANSFER
Occurs between a METAL (low ionisation energy — readily loses electrons) and a NON-METAL (high electron affinity — readily gains electrons). Metal LOSES electron(s) → CATION (+). Non-metal GAINS electron(s) → ANION (−). Electrostatic ATTRACTION between opposite charges forms the BOND.
Formation of NaCl (Sodium Chloride)
Na (Z=11): 2, 8, 1 → loses 1e⁻ → Na⁺ (2, 8) — NEON configuration (stable). Cl (Z=17): 2, 8, 7 → gains 1e⁻ → Cl⁻ (2, 8, 8) — ARGON configuration (stable). Na⁺ + Cl⁻ → NaCl (held by ionic/electrostatic bond).
Formation of MgO (Magnesium Oxide)
Mg (Z=12): 2, 8, 2 → loses 2e⁻ → Mg²⁺ (2, 8). O (Z=8): 2, 6 → gains 2e⁻ → O²⁻ (2, 8). Mg²⁺ + O²⁻ → MgO.
Formation of CaCl₂ (Calcium Chloride)
Ca (Z=20): 2, 8, 8, 2 → loses 2e⁻ → Ca²⁺ (2, 8, 8). Each Cl (Z=17): 2, 8, 7 → gains 1e⁻ → Cl⁻. Ca²⁺ + 2Cl⁻ → CaCl₂. 'One Ca²⁺ ion attracts TWO Cl⁻ ions — the formula is CaCl₂, not CaCl.'
Properties of Ionic Compounds
- HIGH melting and boiling points — strong electrostatic forces hold the crystal lattice. Much energy needed to break.
- Conduct electricity when MOLTEN (liquid) or DISSOLVED IN WATER — ions FREE to move.
- Do NOT conduct in SOLID state — ions LOCKED in fixed positions.
- BRITTLE — when force shifts layers, like charges repel → crystal SHATTERS.
- Usually SOLUBLE IN WATER (water molecules hydrate and separate ions).
3. Covalent Bond — Electron SHARING
Occurs between TWO NON-METALS with similar electronegativities. Neither transfers — they SHARE valence electrons. Each atom COUNTS the shared electrons toward its octet.
Types of Covalent Bonds
| Bond Type | Shared Pairs | Example | Lewis Structure |
|---|---|---|---|
| Single | 1 pair (2e⁻) | H₂, Cl₂, CH₄, H₂O | H−H, Cl−Cl |
| Double | 2 pairs (4e⁻) | O₂, CO₂ | O=O, O=C=O |
| Triple | 3 pairs (6e⁻) | N₂ | N≡N |
Key Examples
H₂: Each H has 1 e⁻. Share 1 pair → both get 2 (duet). Cl₂: Each Cl has 7 valence e⁻. Share 1 pair → both get 8 (octet). O₂: Each O has 6 valence e⁻. Share 2 pairs → both get 8. N₂: Each N has 5 valence e⁻. Share 3 pairs → both get 8. 'N₂ has the STRONGEST bond — a triple bond with bond energy 941 kJ/mol.' CH₄ (Methane) : C has 4 valence e⁻, shares with 4 H atoms → each H gets 2, C gets 8. H₂O: O has 6 valence e⁻, shares with 2 H atoms → each H gets 2, O gets 8. CO₂: C has 4 valence e⁻, shares 2 pairs with each O → all atoms get 8.
Properties of Covalent Compounds
- LOW melting and boiling points — weak INTERMOLECULAR forces between separate molecules. WITHIN-molecule bonds are strong. BETWEEN-molecule forces are weak.
- Do NOT conduct electricity — no free ions or electrons (except graphite — delocalised electrons between layers).
- Usually INSOLUBLE IN WATER — soluble in ORGANIC SOLVENTS.
4. Coordinate (Dative) Bond
A covalent bond where BOTH shared electrons come from the SAME atom. Once formed, it is identical to a regular covalent bond. Example — NH₄⁺ (Ammonium ion) : NH₃ has a LONE PAIR on nitrogen. H⁺ (no electrons) accepts this lone pair → N→H coordinate bond. Example — H₃O⁺ (Hydronium ion) : H₂O donates a lone pair to H⁺.
5. Ionic vs Covalent — Quick Comparison
| Property | Ionic | Covalent |
|---|---|---|
| Formation | Electron TRANSFER | Electron SHARING |
| Between | Metal + Non-metal | Non-metal + Non-metal |
| MP/BP | HIGH | LOW |
| Conductivity | Only when molten/dissolved | NO (except graphite) |
| Solubility | Water | Organic solvents |
| Physical state | Crystalline solid | Gas, liquid, or soft solid |
6. Common Mistakes to Avoid
- 'NaCl molecules exist independently' — NaCl is an IONIC CRYSTAL LATTICE. The formula represents the simplest RATIO (1:1) — not a discrete molecule.
- 'Covalent bonds are weak' — WITHIN-molecule covalent bonds are VERY STRONG. The INTERMOLECULAR forces are WEAK — that's why BP/MP are low.
- 'Ionic compounds never conduct electricity' — They DO conduct — but ONLY when MOLTEN or DISSOLVED (ions FREE to move). NEVER as solids.
- 'CaCl has the same formula as NaCl' — Ca²⁺ needs TWO Cl⁻ ions to balance charge. Formula is CaCl₂. Always cross-multiply valencies.
7. AP SSC Exam Focus
| Topic | Marks | Type |
|---|---|---|
| Ionic bond formation (NaCl, MgO, CaCl₂) | 4-5 | Equation + explanation |
| Covalent bond examples (H₂, O₂, CH₄) | 4-5 | Lewis structures |
| Ionic vs Covalent properties | 3-4 | Table comparison |
| Coordinate bond (NH₄⁺) | 2-3 | MCQ or Short |
Key Memory Aids
- IONIC = Transfer (think: I Transferred money). Metal to Non-metal.
- COVALENT = Sharing (think: Co-workers Share). Non-metal with Non-metal.
- Ionic compounds: 'HIGH and MIGHTY' — HIGH MP/BP. MIGHT conduct when mobile (molten/dissolved).
- Covalent compounds: 'LOW and LONELY' — LOW MP/BP. LONELY molecules (weakly attracted to each other).
Valency vs Ionic Charge
Valency is the COMBINING CAPACITY (no sign). Ionic charge has a SIGN. Na has valency 1, forms Na⁺ (charge +1). Cl has valency 1, forms Cl⁻ (charge −1). Mg has valency 2, forms Mg²⁺. O has valency 2, forms O²⁻. Al has valency 3, forms Al³⁺. N has valency 3, forms N³⁻. 'Use VALENCY when writing formulas (cross-multiply the numbers). Use IONIC CHARGE when explaining the bond (opposite charges attract).' Example: Al³⁺ and O²⁻ → cross-multiply valencies → Al₂O₃ (Al: 2 atoms, O: 3 atoms). Check charges: 2(+3) + 3(−2) = +6 −6 = 0 (correct).
