How would you distinguish experimentally between an alcohol and a carboxylic acid?
Hint. Think of a reagent that reacts with one of these functional groups but not the other, producing something you can visibly see or test for.
Step 1 — Choose a suitable test reagent. Sodium hydrogencarbonate (baking soda) reacts with carboxylic acids but not with alcohols.
Step 2 — Describe what happens with each. Adding the sample to sodium hydrogencarbonate solution: a carboxylic acid produces brisk effervescence of carbon dioxide gas (which turns limewater milky), since the acid reacts with the hydrogencarbonate, while an alcohol shows no reaction at all — no bubbling.
✦ Answer: Add sodium hydrogencarbonate solution to each sample — a carboxylic acid fizzes vigorously (releasing CO₂, confirmed by turning limewater milky), while an alcohol shows no reaction.
Where students slip. Relying only on litmus paper — while a carboxylic acid does turn blue litmus red and alcohol doesn't, the effervescence test with sodium hydrogencarbonate is the more decisive, unambiguous distinguishing test.
